Dota, LoL and CSGO rely on the strategy and skill of the players against other players, not really player vs intelligent game. The games are only as intelligent as those people controlling the opposing team/heroes. I mean if you count CS:GO you would have to count every first person shooter competitive online game. Day of Defeat, Team Fortress Classic, etc.
I just started playing Alien Isolation and I love the AI aspect of the game, how much you have to rely on stealth and distraction to survive, the alien always seems nearby. Very different from most hack and slash games where you can brute force your way through most encounters. You actually will feel like you are in a movie, which I believe was their intention as sometimes you lose control of your character for a brief moment and it goes to a "cut-scene"
Of course Portal was a great puzzle game that really got you thinking in order to beat some of the levels. My favorite parts were where you had to place a portal on the ground, and another on the wall and get up high and jump into it, in order to build up speed to launch yourself out of the second portal.